Dehydrogenation of formic acid by Ir–bisMETAMORPhos complexes: experimental and computational insight into the role of a cooperative ligand† †Electronic supplementary information (ESI) available. CCDC 1020151. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4sc02555e Click here for additional data file. Click here for additional data file.

Dehydrogenation of Formic Acid by Ir-bisMETAMORPhos Complexes: Experimental and Computational Insight in the Role of a Cooperative Ligand Sander Oldenhof, Martin Lutz, Bas de Bruin, Jarl Ivar van der Vlugt, Joost N. H. Reek a S. Oldenhof, Prof. Dr. B. de Bruin, Dr. Ir. J. I. van der Vlugt, Prof. Dr. J. N. H. Reek, van ’t Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, 1098 XH, Amsterdam (The Netherlands), E-mail: [email protected] b Dr. M. Lutz, Bijvoet Center for Biomolecular Research Utrecht University ̧ Padualaan 8, 3584 CH Utrecht (The Netherlands). Table of content